A series of Er~(3+)-activated SrLaGa_3O_7 single crystal fibers for mid-infrared laser application

A multidisciplinary approach for the production and characterization of a series of high concentration Er~(3+)activated SrLaGa_3 O_7(abbreviated as Er:SLGO) crystal fibers is shown to have a great promise for implementation in mid-infrared laser applications.The current approach includes the design and formation of unique layered tetrahedral network structures with several kinds of rare earth(RE) ions including Er ions distributing statistically between layers,such as Er:SLGO,Er,Nd:SLGO,Er,Yb,Ho:SLGO,Er,Eu:SLGO and Er,Ho:SLGO.Five kinds of Er:SLGO crystal fibers were designed to grow via a micropulling down method.Spectroscopic analyses show that Er,Yb,Ho:SLGO and Nd,Er:SLGO crystal fibers were superiorly endowed with inhomogeneous broadening absorption and strong emission.The unique structural components design enables the generation of improved absorption and emission recombination,and the inhibition of self-termination as well.Generally,the use of structural components design may warrant high-efficiency emissions in RE-doped crystal fibers.     

Amino-functionalized magnetic bacterial cellulose/activated carbon composite for Pb2+ and methyl orange sorption from aqueous solution

A new nanostructured amino-functionalized magnetic bacterial cellulose/activated carbon(BC/AC)composite bioadsorbent(AMBCAC)was prepared for removal of Pb~(2+)and methyl orange(MO)from aqueous solution.The results demonstrated that the equilibrium adsorption capacity(q_e)for Pb~(2+)obviously increases by 2.14 times after introduction of amino groups,the optimum p H for Pb~(2+)and MO adsorption was 5.0 and 3.0,respectively,and the q_eof AMBCAC was 161.78 mg g~(-1)for Pb~(2+)and 83.26 mg g~(-1)for MO under the optimal conditions in this investigation.The kinetics and adsorption isotherm data of the sorption process were well fitted by pseudo-second-order kinetic model and Langmuir isotherm respectively.The thermodynamic results(the Gibbs free energy change G0,the enthalpy change H0,the entropy change S0)implied that the adsorption process of Pb~(2+)and MO was feasible,endothermic and spontaneous in nature.These results support that the AMBCAC composite developed in this work can provide a cheap and efficient way for easy removal of both Pb~(2+)and MO as a promising adsorbent candidate for wastewater treatment.     

Schedule risk analysis of infrastructure projects: A hybrid dynamic approach

Schedule risk is a major concern in infrastructure project management. Existing studies have proposed several models for schedule risk analysis, but few efforts have been made on the dynamics and uncertainty of risks and the generality and practicability of the model. To fill the research gaps, this study develops a hybrid dynamic approach for investigating the effect of risks on infrastructure project schedule performance. This approach combines system dynamics (SD) and discrete event simulation (DES) which have mainly been used to analyze the macroscopic and microcosmic construction issues in isolation, respectively. The model is then verified by data which is collected from a bridge construction project. As an application example, the effect of four selected risks on the schedule was explored. The results show that the proposed SD-DES model could be ease of modifying the model to reflect real situation, performing various sensitivity and uncertainty analysis, and showing simulation results more effectively.     

The role of Pt loading on reduced graphene oxide support in the polyol synthesis of catalysts for oxygen reduction reaction

Common carbon-blacks have shown insufficient stability as cathodic catalyst supports for proton exchange membrane fuel cells (PEMFCs). In this regard, alternative supports have been proposed and, specifically graphene or reduced graphene oxide (rGO), have attracted special attention. Herein, a set of electrocatalysts using reduced graphene oxide (rGO) as support is synthetized by a modified polyol method. The influence of Pt loading on the support is studied and compared with conventional supports, considering Pt particle morphologies and oxygen reduction reaction (ORR) performance in rotating disk electrode (RDE). Despite Pt average particle size typically increases with the Pt loading, 30 wt% of Pt on rGO is the optimal Pt loading, yielding the highest ORR activity among the rGO-supported electrocatalysts. These results show that both Pt loading and type of support greatly impact on the morphology and electrochemical performance of Pt nanoparticles.     

Three-dimensional porous SnO2@NC framework for excellent energy conversion and storage

SnO₂-based materials are deemed to be attractive electrodes for lithium/sodium ion batteries (LIBs and SIBs) and electrocatalytic CO₂ reduction reaction (CRR) because of high energy density and large abundance. However, the practical application of the SnO₂-based materials is prevented by low electrical conductivity and large volume change. Herein, we construct a three-dimensional (3D) porous network with SnO₂ nanoparticles into N-doped carbon (namely P–SnO₂@NC) synthesized by freeze drying followed by a pyrolyzation process. In the composite, the 3D hierarchical framework can facilitate the ion penetration and gas diffusion. In addition, the NC network can optimize the conductivity of the material and suppress the electrode material to fall off from the electrode. Therefore, the electrode delivers excellent electrochemical properties with high capacities of 510 mA h g⁻¹ after 1000 cycles for LIBs and 497 mA h g⁻¹ after 500 cycles for SIBs. Furthermore, the electrode shows high selectivity for CRR with a large coulombic efficiency (CE) of 52.7% for HCOOH at 0.6 V.     

基于模糊综合评价的景区解说设施优化研究

目的 系统地研究景区解说设施评价体系,建立合理完善的评价方法,为景区解说设施的优化升级提供科学的理论支撑.方法 选取泉州市崇武古城的解说设施为研究对象,以SERVQUAL(服务质量)模型为基础建立解说设施满意度评价体系,借助主成分分析、模糊综合评价以及IPA分析法3种方法,探索景区解说设施满意度及其影响因素.结论 研究表明,构成景区解说设施满意度评价体系的一级指标主要为有形性(UA)、保证性(UB)、移情性(UC)、可靠性(UD),四者的权重由大到小依次为UB>UA>UD>UC;泉州崇武古城景区解说设施满意度评价结果为良好,基本达到旅游解说要求.但是解说设施的有形性方面亟待提升,在视觉效果上的满意度相对较低,影响游客对古城景区的满意度.     

Enhanced stability for preferential oxidation of CO in H2 under H2O and CO2 atmosphere through interaction between iridium and copper species

Preferential oxidation of CO (CO-PROX) is one of the most investigated methods for reducing residual CO in H₂-rich stream to acceptable level in proton exchange membrane fuel cells. However, development of catalyst with high stability under simulated practical conditions is still challenging. Herein, a series of Cu_xCe_1-xO₂ (x = 0, 0.05, 0.09, 0.17) supported Ir catalysts were prepared and 1 wt%Ir/Cu_0.09Ce_0.91O₂ exhibited full conversion of CO in a wide temperature window (80–180 °C), excellent stability and resistance to CO₂ and H₂O poison. Characterization results reveal that the superior performance was mainly associated with the interaction between Ir and Cu species, which resulted in that the adsorbed H₂O on Ir sites was activated to react with adsorbed CO on Cu sites to form easily decomposable bicarbonates and formate species instead of main intermediate of carbonates for 1 wt% Ir/CeO₂ and Cu_0.09Ce_0.91O₂. This work provides a new sight for developing high-performance heterogeneous catalysts.     

基于节点1-邻居图相似性的社会网络匿名技术

利用传统的k匿名技术在社会网络中进行隐私保护时会存在聚类准则单一、图中数据信息利用不足等问题. 针对该问题, 提出了一种利用Kullback-Leibler (KL)散度衡量节点1-邻居图相似性的匿名技术(anonymization techniques for measuring the similarity of node 1-neighbor graph based on Kullback-Leibler divergence, SNKL). 根据节点1-邻居图分布的相似性对原始图节点集进行划分, 按照划分好的类进行图修改, 使修改后的图满足k匿名, 完成图的匿名发布. 实验结果表明, SNKL方法与HIGA方法相比在聚类系数上的改变量平均降低了17.3%, 同时生成的匿名图与原始图重要性节点重合度保持在95%以上. 所提方法在有效保证隐私的基础上, 可以显著的降低对原始图结构信息的改变.     

我国测绘基准的历史与现状

对我国测绘基准的内容、定义及实现进行了简要的论述,同时也对这些基准所存在的问题进行了概括。     

德化陶瓷学院图书馆建筑设计随笔

德化陶瓷学院图书馆的建筑设计以突出以人为本及突出人、建筑、环境三者的和谐组合为主导思想,强调使用功能空间的优化组合及空间的深化,和建筑造型、景观环境相结合的整体设计。构筑建筑的自身魅力及良好的环境效应。